- The kinetic theory of matter explains the behavior and movement of particles in different states of matter.
- Matter is anything that has mass and occupies space.
- Matter is made up of tiny particles such as atoms, molecules, and ions.
States of Matter
There are four states of matter: Solids, Liquids, Gases, and Plasma.
The differences in their properties depend on:
- Kinetic energy of particles
- Force of attraction between particles
Solids
- Fixed shape, cannot flow.
- Particles are closely packed and cannot move freely.
- Cannot be compressed, as particles have no space to move into.
Liquids
- Flow and take the shape of their container.
- Particles move around each other but remain close together.
- Cannot be compressed, as particles have little free space.
Gases
- Flow and completely fill their container.
- Particles move quickly in all directions.
- Can be compressed, as particles are far apart with space to move into.
Phase Changes
Melting
- When heat is applied to a solid, the binding forces loosen and the crystalline structure collapses.
- The temperature at which this occurs is the melting point.
- Impurities lower the melting point and freezing point.
Evaporation
- Occurs when liquid particles at the air‑liquid interface escape into the atmosphere.
- Happens at all temperatures, but the rate increases with temperature.
- Depends on the nature of the liquid: covalent liquids evaporate more readily than electrovalent liquids.
Vapor Pressure
- In a closed system, evaporated particles collide with each other and the container walls, exerting pressure.
- At saturation, the rate of evaporation equals the rate of condensation → saturated vapor pressure (SVP).
- Depends on temperature and nature of the liquid.
Boiling
- As a liquid is heated, evaporation increases and SVP rises.
- When SVP = atmospheric pressure, bubbles form and the liquid boils.
- The temperature at this point is the boiling point.
Factors Affecting Boiling Point:
- Impurities: Increase boiling point.
- Atmospheric pressure:
- Higher pressure → higher boiling point.
- Lower pressure → lower boiling point.
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